Tales of Suspense Vol.1 #82
Tony Stark flies into Washington D.C. to present himself to the hearing in his Iron Man armor, however on the way he is attacked by the newly revived Titanium Man who was launched into Washington D.C. by the Soviets.
The Adaptoid escapes from his AIM creators and invades Avengers Mansion to attack Captain America.
Printed: Oct 1966
Writers: Stan Lee
Art: Gene Colan and Frank Giacoia
Cover: Jack Kirby and Frank Giacoia