Amazing Spider-Man Vol.1 #107
Spider-Man faces off against the upgraded Spider-Slayer; Spider-Man defeats all four leaders, then returns to Smythe's hideout, where he finds Smythe inside the Spider Slayer; And if he survives this bout, he'll have a few words for J. Jonah Jameson when he's done.
Printed: Apr 1972
Writers: Stan Lee
Art: John Romita Sr. and Frank Giacoia
Cover: John Romita Sr. and Frank Giacoia