Tales of Suspense Vol.1 #83
While battling the Titanium Man in Washington D.C., Iron Man soon finds that Pepper Potts, the girl he loves, is caught in the Titanium Man's paralyzer ray.
The Adaptoid, posing as Cap, is attacked by the Tumbler. Cap manages to defeat both.
Printed: Feb 1967
Writers: Stan Lee
Art: Gene Colan, Jack Abel [as Gary Michaels], Jack Kirby, and Dick Ayers
Cover: Gene Colan and Jack Abel